China Adsorbent Material Manufacturer · 10+ Years · ISO 9001

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3A Molecular Sieve

3A molecular sieve is a potassium-exchanged A-type zeolite with a 3 Å pore opening. It adsorbs water while excluding larger molecules such as ethanol, ethylene and propylene.

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3A Molecular Sieve specifications

Property Unit Bead Ø1.6–2.5 mm Bead Ø3.0–5.0 mm Pellet 1/16" Pellet 1/8" Test condition
Static water adsorption % wt ≥ 21.5 ≥ 21.5 ≥ 21.5 ≥ 21.5 RH 75%, 25 °C
Bulk density g/ml ≥ 0.75 ≥ 0.75 ≥ 0.70 ≥ 0.70 Tapped
Crush strength N ≥ 35 ≥ 100 ≥ 40 ≥ 90 Average of 25 beads
Loss on attrition % wt ≤ 0.10 ≤ 0.10 ≤ 0.20 ≤ 0.20 —
Loss on ignition % wt ≤ 1.5 ≤ 1.5 ≤ 1.5 ≤ 1.5 550 °C, 1 h
Particle size ratio % ≥ 98 ≥ 98 ≥ 98 ≥ 98 In stated size range
Typical values. Each lot ships with a COA.

Where is 3A Molecular Sieve used?

3A molecular sieve is used wherever water must be removed without adsorbing the main product: ethanol, cracked gas and olefins, insulating glass and refrigerants.

Ethanol dehydration

Ethanol dehydration

Recommended: Bead 3.0–5.0 mm

PSA drying of fuel ethanol to ≥ 99.5%.

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Cracked gas & olefins

Cracked gas & olefins

Recommended: Bead 3.0–5.0 mm / Pellet 1/8″

Drying ethylene, propylene and butadiene without polymerisation.

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Insulating glass

Insulating glass

Recommended: Bead 1.6–2.5 mm

Desiccant fill for spacer bars.

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Refrigerant drying

Refrigerant drying

Recommended: Bead 1.6–2.5 mm / Pellet 1/16″

Filter-drier cores for refrigeration circuits.

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3A Molecular Sieve vs other grades: which do you need?

Choose 3A when co-adsorption of your product must be avoided; choose 4A for general drying where only H₂O and CO₂ matter, 5A or 13X when you need larger molecules removed as well.

Grade Pore Adsorbs Typical use
3A (this product) 3 Å H₂O, NH₃ Ethanol, olefins, insulating glass
4A 4 Å H₂O, CO₂, H₂S, C₂H₆ Natural gas, air, refrigerant drying
5A 5 Å n-paraffins, CO₂ PSA hydrogen, n/iso-paraffin separation
13X ≈ 10 Å H₂O + CO₂ together, mercaptans Air pre-purification, gas sweetening

What is 3A Molecular Sieve?

3A molecular sieve is a synthetic potassium A-type zeolite (KA) whose 3 Å pores let water in and keep almost every other molecule out. It is made by exchanging part of the sodium in 4A zeolite for potassium, which narrows the pore opening from 4 Å to about 3 Å.

Chemical type

Potassium A-type zeolite

≈ 0.6K₂O · 0.4Na₂O · Al₂O₃ · 2SiO₂

Adsorbs

H₂O, NH₃

Molecules smaller than 3 Å

Excludes

Ethanol, C₂H₄, C₃H₆, CO₂

Larger molecules pass through

How does 3A Molecular Sieve work?

3A molecular sieve works by size exclusion: a water molecule (≈ 2.8 Å) fits through the 3 Å pore and is held on the crystal surface, while ethanol (≈ 4.4 Å) and olefins are physically too large to enter.

  • Wet stream enters the bed — gas or liquid flows through a packed column of 3A beads.
  • Water is trapped in the pores — polar H₂O is adsorbed strongly; outlet moisture drops to below the target dew point.
  • Product passes through untouched — no co-adsorption, so no product loss and no coke-forming polymerisation.

How is 3A Molecular Sieve manufactured?

We make 3A molecular sieve in six steps in our own plant, from 4A zeolite powder to sealed drums, and test every lot before it ships.

01Synthesis

Na-A (4A) zeolite crystallised from sodium silicate and aluminate.

02Potassium exchange

Na⁺ replaced with K⁺ — this sets the 3 Å pore.

03Forming

Blended with clay binder, rolled into beads or extruded into pellets.

04Activation

Dried and calcined in a rotary kiln at high temperature.

05Screening

Sieved to size range; fines and broken beads removed.

06Test & pack

Adsorption, crush strength and moisture tested; sealed hot.

When should you use 3A Molecular Sieve?

Use 3A molecular sieve whenever you must remove water from a stream whose main molecules are small or reactive enough that a 4A sieve would also adsorb them.

Ethanol dehydration

PSA drying of fuel ethanol to ≥ 99.5% — ethanol stays out of the pores.

Cracked gas & olefins

Drying ethylene, propylene and butadiene without polymerisation in the bed.

Insulating glass

Desiccant in spacer bars; takes up water, not the argon or air fill.

Polar liquids & refrigerants

Drying methanol and refrigerant circuits in filter-driers.

How do you regenerate 3A Molecular Sieve?

Regenerate 3A molecular sieve by heating the bed with a dry purge gas until the outlet dew point recovers; in PSA ethanol units it is regenerated by pressure swing instead.

Temperature

200–300 °C

Purge gas

Dry N₂ / product gas

Bed life

3–5 years


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Need a non-standard grade?

Send your operating conditions — we reply with a grade recommendation and quote within 24 hours.