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Refining & petrochemicals

Molecular Sieve for Ethanol Dehydration

Core Adsorbent supplies 3A molecular sieve for dehydrating ethanol beyond the azeotrope to fuel-grade and anhydrous specifications in PSA and TSA units.

3A

Main dehydration grade

≈ 95 %

Azeotrope limit of distillation

15–35 days

Delivery time

1 t

MOQ per grade

01 Overview

Why is 3A molecular sieve used for ethanol dehydration?

Distillation stops at the ethanol–water azeotrope of about 95 % ethanol. 3A molecular sieve removes the remaining water because water enters its 3 Å pores while ethanol is excluded, so ethanol is not co-adsorbed and the product reaches fuel-grade purity.

Main grade3A Molecular Sieve
ProcessVapour-phase PSA or liquid-phase TSA
Why 3AExcludes ethanol, admits water
FeedNear-azeotropic ethanol
SupportInert Alumina Ceramic Ball

02 Challenges

What limits ethanol dehydration?

Four issues that set yield, energy use and bed life.

Distillation column

The azeotrope

Distillation alone cannot pass about 95 % ethanol.

Ethanol product tank

Co-adsorption

A larger-pore sieve would adsorb ethanol and lose product.

Worn adsorbent beads

Bead strength

Frequent pressure swings wear beads and create fines.

Fermentation tanks

Contaminants

Fusel oils and acids from fermentation shorten bed life.

03 Solutions

Recommended grades for ethanol plants

01

Fuel ethanol plants

Typical requirement: reach fuel-grade ethanol from azeotropic feed

02

Pharmaceutical and solvent ethanol

Typical requirement: anhydrous ethanol for chemical use

03

Other alcohols and solvents

Typical requirement: dry small polar solvents

04 Selection guide

Ethanol dehydration adsorbent selection

Full specifications are on each product page.

ProductUseKey figure
3A Molecular SieveEthanol and methanol dehydration3 Å pore, static H₂O ≥ 21.5 %
4A Molecular SieveDrying solvents too large for 4 ÅStatic H₂O ≥ 22.5 %
Inert Alumina Ceramic BallBed support17–99 % Al₂O₃

05 Key properties

3A data for ethanol units

3 Å

Pore that excludes ethanol

≥ 21.5 %

Static water adsorption

≈ 95 %

Azeotrope limit the sieve overcomes

COA

Lot test report with every shipment

Product data from our specifications; azeotrope value is general chemistry. Full data: 3A Molecular Sieve.

06 From our plant

What you receive

The adsorbent, the packing and the plant it ships from.

3A molecular sieve beads for ethanol dehydration
Molecular sieve packed in steel drums
Adsorbent packed in jumbo bags
Adsorbent forming line at the Core Adsorbent plant
Container loading of adsorbent for export

Photos are replaced with real product, packing and plant images as they become available.

07 Support

Customisation and engineering support

  • Unit support — send feed composition, flow and cycle; we propose bead size and bed loading.
  • Grade matching — send the data sheet of the adsorbent you use now; we propose an equivalent grade.
  • Complete bed supply — main adsorbent, guard layer and ceramic balls in one shipment, under one COA system.
  • Packing — steel drums or jumbo bags, sealed against moisture; samples from 5–10 kg.

08 Related solutions

More refining and petrochemicals solutions

09 Recommended products

Products for ethanol dehydration

10 FAQ

Molecular Sieve for Ethanol Dehydration FAQ

Can’t find your answer? Ask our sales engineer.

Why not use 4A for ethanol?

Ethanol can enter 4A pores and be co-adsorbed; 3A Molecular Sieve excludes it.

Can 3A dry methanol?

Yes, 3A Molecular Sieve is also used for methanol and other small alcohols.

What bead size is used?

Typically Ø 2.5–5.0 mm for vapour-phase PSA beds; confirm with your unit design.

How long does the sieve last?

It depends on cycling and feed impurities; share operating data for an estimate.