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Industrial gases

Molecular Sieve for N₂O Removal in Air Separation

Core Adsorbent supplies CaX molecular sieve as an added layer in air pre-purification units, removing N₂O and trace hydrocarbons that standard 13X lets through.

CaX

N₂O removal layer

≥ 18.0 ml/g

Static N₂ adsorption

15–35 days

Delivery time

1 t

MOQ per grade

01 Overview

Which molecular sieve removes N₂O in air pre-purification?

CaX (calcium-exchanged X) molecular sieve is added above the 13X APG layer in a pre-purification unit. Its calcium sites hold N₂O and trace hydrocarbons that pass a standard 13X layer, reducing the risk of these compounds accumulating in the cold box.

N₂O layerCaX Molecular Sieve
CO₂ and water13X APG Molecular Sieve
Inlet waterActivated Alumina Desiccant
RegenerationHeated waste nitrogen
Static N₂ adsorption≥ 18.0 ml/g (760 mmHg, 25 °C)

02 Challenges

Why does N₂O matter in air separation?

Trace components that pass the pre-purifier collect in the coldest sections.

Cold box of an air separation unit

N₂O slip

N₂O is weakly held by 13X and breaks through before CO₂.

Reboiler-condenser

Accumulation

N₂O and hydrocarbons concentrate in the reboiler and can deposit as solids.

Liquid oxygen storage

Safety margin

Hydrocarbon accumulation in liquid oxygen is a known safety concern.

Pre-purifier vessels

Retrofits

Existing pre-purifiers must add capacity without new vessels.

03 Solutions

Recommended layers for N₂O control

01

New pre-purifiers

Typical requirement: design for CO₂, water and N₂O removal

02

Retrofit of existing units

Typical requirement: add N₂O removal within the existing vessel

03

Hydrocarbon control

Typical requirement: reduce trace hydrocarbons reaching the cold box

04 Bed configuration

Typical pre-purifier bed with N₂O layer

Air flows upward; layer heights depend on air quality and cycle.

Layer (top to bottom)ProductFunction
TopCaX Molecular SieveN₂O and trace hydrocarbons
Middle13X APG Molecular SieveCO₂ and remaining water
BottomActivated Alumina DesiccantBulk water removal

05 Key properties

CaX data for pre-purifiers

≥ 18.0 ml/g

Static N₂ adsorption (760 mmHg, 25 °C)

Ca-X

Calcium-exchanged X framework

Upflow

Typical adsorption direction

COA

Lot test report with every shipment

Product data from our specifications; layer design depends on air quality and cycle. Full data: CaX Molecular Sieve.

06 From our plant

What you receive

The adsorbent, the packing and the plant it ships from.

CaX molecular sieve beads, close-up
Molecular sieve packed in steel drums
Adsorbent packed in jumbo bags
Adsorbent forming line at the Core Adsorbent plant
Container loading of adsorbent for export

Photos are replaced with real product, packing and plant images as they become available.

07 Support

Customisation and engineering support

  • Retrofit proposal — send your current bed design and cycle; we propose the CaX layer height.
  • Grade matching — send the data sheet of the adsorbent you use now; we propose an equivalent grade.
  • Complete bed supply — main adsorbent, guard layer and ceramic balls in one shipment, under one COA system.
  • Packing — steel drums or jumbo bags, sealed against moisture; samples from 5–10 kg.

08 Related solutions

More industrial gases solutions

09 Recommended products

Products for N₂O removal in air separation

10 FAQ

Molecular Sieve for N₂O Removal in Air Separation FAQ

Can’t find your answer? Ask our sales engineer.

Why not just add more 13X?

13X holds N₂O weakly; adding CaX targets N₂O directly without enlarging the vessel.

Where is the CaX layer placed?

Above the 13X APG layer, at the outlet end of an upflow adsorber.

Does CaX change regeneration?

It regenerates with the same heated waste nitrogen; confirm temperatures with your process licensor.

Can you supply all three layers?

Yes — Activated Alumina Desiccant, 13X APG Molecular Sieve and CaX Molecular Sieve together.